Product ID:REG UNLEADED GASOLINE,CODE:02104/02110/02120/(SUPPLEMENT)
MSDS Date:01/01/1988
FSC:9130
NIIN:00-148-7103
MSDS Number: BVGZJ

SHELL OIL COMPANY

1 SHELL PLAZA
HOUSTON, TX 77001
US

Emergency Phone: 713-473-9461 (24 HOUR EMERGENCY)

Info Phone: 713-241-4819

Preparer: J.C.WILLETT

Cage: 54527

SHELL OIL COMPANY

2463 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

GASOLINE, REGULAR UNLEADED

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 100%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM/500STEL;9394

MIXTURE, ALKANES, CYCLOALKANES, ALKENES & AROMATIC

Fraction By Weight: BALANCE

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 0-25%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150STEL;9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 0-25%

OSHA PEL 200 PPM; Z-2

ACGIH TLV: S, 50 PPM; 9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 0-4%

OSHA PEL SEE 1910.1028

ACGIH TLV: 10 PPM; A2; 9394

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

HEXANE (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: 0-3%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9394

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: 0-15%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 0-5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9394

CYCLOHEXANE (SARA III)

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: 0-1%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM, 9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 0-3%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/125STEL;9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

NAPHTHALENE (SARA III)

CAS: 91-20-3

RTECS: QJ0525000

Fraction By Weight: 0-1%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM/15 STEL; 9394

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

STYRENE, MONOMER (SARA III)

CAS: 100-42-5

RTECS: WL3675000

Fraction By Weight: 0-4%

OSHA PEL 100 PPM

ACGIH TLV: S,50PPM/100STEL;9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CONTENT OF GASOLINE COMPONENTS WILL VARY;INDIVIDUAL

RTECS: 9999999ZZ

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYE:MIN IRRIT. SKIN:PROLONG/REPEAT LIQ
CONTACT CAN CAUSE DEFATTING & DRYING RESULTING IN IRRIT/DERM.
INHAL:NOSE/THROAT/RESP TRACT IRRIT.MAY PRODUCE LIVER/KIDNEY
DAMAGE.HIGH VAP CONCEN MAY PRODUCE CNS DEPRESS.
INGEST:HARMFUL/FATAL.VOMIT,ASPIRATION OF VOMITUS INTO LUNGS
RESULTING IN ASPIRATION PNEUMONITIS.
Explanation of Carcinogenicity:CONTAINS BENZENE. PER IARC DETERMINES
GASOLINE CARCINOGENIC (GROUP 2B).
Effects of Overexposure:CNS DEPRESS:GIDDINESS,HEAD,DIZZ,NAU.ALSO
UNCONSCIOUSNESS,DEATH. ASPIRATION PNUITIS:COUGHING,LABORED
BREATHING,CYANOSIS(BLUISH SKIN),DEATH.KIDNEY DAMAGE:CHANGES IN
URINE OUTPUT,URINE APPEARANCE,EDEMA. LIVER DAMAGE:LOSS OF
APPETITE,JAUNDICE(YELLOWISH SKIN COLOR),PAIN IN UPPER ABDOMEN ON
RIGHT SIDE.
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE/SKIN/RESP
DISORDERS. IMPAIRED LIVER & KIDNEY FUNCTIN(S) FROM PRE-EXISITNG
DISORDERS.

First Aid:EYE:FLUSH W/WATER FOR 15MINS OPENING EYELIDS.GET MED ATTN.
SKIN:FLUSH W/WATER WHILE REMOVING CONTAMIN CLOTH/SHOES.WASH W/SOAP
& WATER.IRRIT PERSISTS GET MED ATTN. INHAL:REMOVE TO FRESH
AIR.PROVIDE OXY GEN IF BREATHING DIFFICULTY.GIVE ARTI RESP IF NOT
BREATHING.GET MED ATTN. INGEST:DO NOT INDUCE VOMIT.IF OCCURS
SPONTANEOUSLY KEEP HEAD BELOW HIPS.GET MED ATTN. (SEE SUPPLEMENTAL)

Flash Point Method:TCC
Flash Point:-40F,-40C
Lower Limits:1.3
Upper Limits:7.6
Extinguishing Media:USE WATER FOG,FOAM,DRY CHEM OR CO2.DO NOT USE
DIRECT STREAM OF WATER,MATL WILL FLOAT & CAN BE REIGN ON SURFACE OF
WATER.
Fire Fighting Procedures:DANGER.EXTREMELY FLAMM.CLEAR AREA OF
PUBLIC.ISOLATE.DO NOT ENTER CONFINED FIRE SPACE W/O FULL BUNKER
GEAR + POS PRESSURE NIOSH APPROVED SCBA.COOL CNTNR W/WATER.
Unusual Fire/Explosion Hazard:VAP HEAVIER THAN AIR/ACCUMULATE IN LOW
AREAS/TRAVEL ALONG GROUND.DON'T WELD/HEAT/DRILL ON/NEAR CNTNR.IF
EMERG REQUIRE DRILLING-SHOULD BE DONE BY TRAIN EMRG PERS

Spill Release Procedures:ELIMINATE ALL IGN SOURCES.GROUND EQPMT.ISOLATE
AREA.WEAR APPROPRIATE RESP/PPE.SHUT OFF SOURCE W/O
RISK.DIKE/CONTAIN.WATER FOG FOR SUPPRESSING VAP.CONTAIN
RUNOFF.REMOVE W/VAC TRUCKS/PUMP TO STORAGE/SAL V VESS.SOAK RESIDUE
W/ABSORBENT.FLUSH W/ATER.
Neutralizing Agent:NONE SPECIFIED BY MFG.

Handling and Storage Precautions:AVOID HEAT/SPARKS/OPEN FLAMES/PILOT
LIGHTS/STRONG OXIDIZING AGENTS.USE EXPLOSION-PROOF VENTI TO PREVENT
VAP ACCUMULATION.ALL EQPMT MUST BE GROUNDED.
Other Precautions:DO NOT SIPHON BY MOUTH.FOR USE AS MOTOR FUEL ONLY.DO
NOT USE AS CLEANING SOLVENT OR NON-MOTOR FUEL.IF MAJOR SPILL OCCURS
GET UPWIND & NOTIFY EMERG PERSONNEL.REMEMBER EXPLOSION & FIRE IS
THE MOST IMMED DANGER.

Respiratory Protection:UNDER CONDITIONS OF POTENTIAL HIGH EXPOSURE USE
OF NIOSH-APPROVED RESP IS RECOMMENDED. PER 29CFR1910.134 OR
29CFR1910.1028 USE EITHER ATM-SUPPLYING RES OR AIR-PURIFING RESP
FOR ORGANIC VAPORS.
Ventilation:USE EXPOLSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:NITRILE RUB, PVA, VITON/NEOPRENE GLOVES.
Eye Protection:CHEM GOGGLES.
Other Protective Equipment:CLOTHING FOR PROTECTION AS NECESSARY.
Work Hygienic Practices:WASH CONTAMIN CLOTH/SHOE PRIOR TO
REUSE.WASHW/SOAP & WATER BEFORE EAT/DRINK/SMOKE/TOILET FACILITIES.
Supplemental Safety and Health
CODE:02121/02122/02123/02127/02150. DOCTOR:IF >2.0ML/KG INGEST & NO
VOMITING EMESIS HSOULD BE INDUCED W/MED SUPERVISION.IF SYMPTOMS
(EX:LOSS OF GAG REFLEX,CONVULSIONS,UNCONSCIOUSNESS) OCCUR BEFORE
EME SIS GASTRIC LAVAGE USING CUFFED ENDOTRACHEAL TUBE SHOULD BE
CONSIDERED.

HCC:F2
Melt/Freeze Pt:M.P/F.P Text:-72F,-58C
Vapor Pres:7-1405PSI
Vapor Density:3.5
Spec Gravity:0.72-0.76
Solubility in Water:NEGLIGIBLE.
Appearance and Odor:BRONZE COLOR, CLEAR & BRIGHT LIQUID, HYDROCARBON
ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES & STRONG
OXIDIZING AGENTS. PREVENT VAPOR ACCUMULATION.
Hazardous Decomposition Products:CARBON MONOXIDE & OTHER UNIDENTIFIED
ORGANIC COMPOUNDS CAN BE FORMED UPON COMBUSTION.

Waste Disposal Methods:NONE SPECIFIED BY MFG. HOWEVER DISPOSE OF IAW
LOCAL, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.